Browsing by Advisor
Now showing items 1-7 of 7
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Cross-coupling reactions: synthesis and photoactivity of enediynes
(2015-02-02)The syntheses of a number of photoactive enediynes using the Sonogashira Coupling reaction are described. Alkynes with different characteristics were coupled to 2-bromoiodobenzene to yield the desired drugs. The enediyne’s ... -
Expansion of the applicability of the Truce-Smiles rearrangement
(2022)The Truce-Smiles rearrangement is a synthetically useful and easily performed reaction which can be used to condense multiple steps of a synthesis. The nucleophilic aromatic substitution in this reaction produces a chiral ... -
Local variation of trace element concentrations in Usnea subfloridana
(2012-11-10)A mensurative study into the local variability of trace element concentrations in the lichen Usnea subjloridana was conducted. Samples were collected from an Abies balsamea located in the Thunder B y region away from any ... -
Ruthenium-Tris(Pyrazolyl)methane complexes as potential candidates for cancer chemotherapy agents
(2009)The MeCN ligands of complex 1 were substitutionally inert, however, under forcing conditions the DMSO ligands of complex 2 were displaced by chelating 1,2-bis(diphenylphosphino)ethane to produce complex 6. Structural ... -
Selected ion flow tube-mass spectrometry in plant volatile compound analysis
(2009-07-20)Four monoterpenes and two monoterpenoids, (+)- and DL-limonene, (1S)-(3) carene, terpinolene, cineol and rose oxide, respectively, were studied using selected ion flow tube-mass spectrometry. Specifically, the reactions ... -
The stereochemical impact of chiral ionic liquids on [2+2] photochemical cycloadditions and aldol reactions
(2020)Eight chiral ionic liquids have been prepared for use as solvents to test whether they can induce enantioselectivity in both photochemical [2+2] cycloadditions and aldol reactions using a variety of starting materials. ... -
Synthesis and applications of room temperature ionic liquids
(2017)A variety of room temperature ionic liquids have been synthesized and applied to various reactions. Four of these ionic liquids were prepared in a chiral manner: [1-butyl-3- methylimidazolium][L-lactate], [1-butyl-3-me ...